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31.
Influence of Chemical Effect on the Kβ/Kα Intensity Ratios and KβEnergy Shift of Co,Ni, Cu,and Zn Complexes 下载免费PDF全文
Chemical effects on the Kβ/Kα intensity ratios and ¢E energy differences for Co, Ni, Cu, and Zn complexes were investigated. The samples were excited by 59.5 keV γ-rays from a 241Am annular radioactive source. K X-rays emitted by samples were counted by an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. We observed the effects of different ligands on the Kβ/Kα intensity ratios and ⊿E energy differences for Co, Ni, Cu, and Zn complexes. We tried to investigate chemical effects on central atoms using the behaviors of different ligands in these complexes. The experimental values of Kβ/Kα were compared with the theoretical and other experimental values of pure Co, Ni, Cu, and Zn. 相似文献
32.
Sevnur Keskin Dogruyol Zekeriya Dogruyol Nergis Arsu 《Journal of polymer science. Part A, Polymer chemistry》2011,49(18):4037-4043
Thioxanthone‐based 9‐(2‐Morpholine‐4yl‐acetyl)‐5‐thia‐napthasen‐12‐one (TX‐MPM) was synthesized and characterized as a one‐component novel visible photoinitiator. Its capability to act as an initiator for the polymerization of methyl methacrylate (MMA) was examined in photoreactor and also daylight. Photophysical properties: fluorescence and phosphorescence emission spectra and fluorescence quantum yield of TX‐MPM (?f = 0.29) were determined. The phosphorescence lifetime was found 131 ms for TX‐MPM and 110 ms for initiator‐attached polymer (PMMA) at 77 K, indicated a π→π* nature of the lowest triplet state. A model compound, morpholino acetonapthone was used as quencher for the triplet states of TX‐MPM and the quenching rate constant was determined (kq = 1.26 × 109 M?1s?1). According to laser flash photolysis studies, intermolecular hydrogen abstraction process was more dominant path to the formation of the initiating radicals. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
33.
Anthracene was used to form an inclusion complex with methylated-β-cyclodextrin (Me-β-CD) in water. In aqueous Me-β-CD solution, typical fluorescence emission of anthracene was observed. Benesi–Hildebrand's method was used to obtain the stoichiometry of the anthracene–Me-β-CD complex. The Stern–Volmer quenching constants, Ksv, and fluorescence quantum yields were calculated according to changes in the fluorescence emission intensity of anthracene–Me-β-CD inclusion complexes by adding various amounts of Pb2+ and Cd2+ salts in water. The Ksv values and fluorescence quantum yields indicate that Pb2+ salts quench the anthracene–Me-β-CD inclusion complexes more efficiently than Cd2+ salts. 相似文献
34.
The entropy generation during the transient laminar natural convection in a square enclosure that is partially heated from a vertical lateral wall is numerically investigated. The active sites referring to the main irreversibility locations are determined. The Boussinesq approximation is used in the natural convection modelling. The effects of Prandtl (Pr) and Rayleigh (Ra) number combinations on the entropy generation are investigated. The study is restricted to the fluids of Prandtl number from 0.01 to 1.0, and Rayleigh numbers in the range of 102–108. It is found that the upper corner of the heated part of the side wall is the active site where the entropy generation initiates due to irreversibilities representing the energy loss. 相似文献
35.
Halit Kantekin Asiye Bakaray Zekeriya Bıyıklıoğlu Meltem Betül Kılıçaslan 《Transition Metal Chemistry》2008,33(2):161-165
A new (E,E)-dioxime, (21Z,22Z)-6,7,9,10,12,13-hexahydro-16H- benzo[h][1,4,7,16,10,13][1, 4,7,16,10,13]dioxadithiadiazacyclooctadecine-21,22(20H,23H)-dione dioxime (H
2
L) has been synthesized by reacting cyanogen-di-N-oxide (2) with (2-{[2-(2-{2-[(7-aminocyclohepta-1,4,6-trien-1-yl)thio]ethoxy}ethoxy)ethyl]thio}phenyl)amine. Mononuclear complexes
of this ligand have been synthesized by reacting the vic-dioxime (H2L) with CuCl2, NiCl2.6H2O and CoCl2.6H2O respectively. The BF2+ capped Ni(II) and Co(III) complexes of the dioxime have been synthesized from. The new compounds were characterized by a
combination of elemental analysis, 1H- and 13C-n.m.r, I.R. and m.s. spectral data. 相似文献
36.
The new 2-[2-(6-tert-butyl-2H-1,3-benzoxazin-3(4H)-yl)ethoxy]ethanol 1 and 2-[2-(6-pentyl-2H-1,3-benzoxazin-3(4H)-yl)ethoxy]ethanol 2 have been synthesized. Axially disubstituted silicon phthalocyanines 3 and 4 have been synthesized by introducing 2-[2-(6-tert-butyl-2H-1,3-benzoxazin-3(4H)-yl)ethoxy]ethanol and 2-[2-(6-pentyl-2H-1,3-benzoxazin-3(4H)-yl)ethoxy]ethanol at the axial positions of silicon(IV) phthalocyanine, respectively. The electrochemical properties of silicon phthalocyanines 3 and 4 were also investigated by cyclic voltammetry (CV) and square wave voltammetry. Voltammetric studies show that while 3 showed two reversible reduction and one irreversible oxidation couples, 4 showed two quasi-reversible reduction and one irreversible oxidation couples. 相似文献
37.
The novel tetrasubstituted metal-free phthalocyanine (6) and metallophthalocyanines (7, 8) bearing four 14-membered tetraaza macrocycles moieties on peripheral positions have been synthesized by cyclotetramerization reaction of phthalonitrile derivative (5) in a multi-step reaction sequence. The new compounds were characterized by a combination of IR, 1H NMR, 13C NMR, UV-vis, elemental analysis and MS spectral data. 相似文献
38.
Zekeriya Bıyıklıoğlu Beytullah Ertem Selami Karslıoğlu Yaşar Gök 《Transition Metal Chemistry》2007,32(5):591-596
The novel (E,E)-dioxime,7,8-bis(hydroxyimino)-1,14-bis(monoaza[8]crown-6)-benzo[f]-4,11-dioxa-1,14-diazadecane[7,8-g]quinoxaline (H2L), has been synthesized by the reaction of 6,7-diamino-1,12-bis(monoaza[18]crown-6)benzo[f]-4,9-dioxa-1,12-diazadecane (4) which has been prepared by the reduction of 6,7-dinitro-1,12-bis(mono-aza[18]crown-6)benzo[f]-4,9-dioxa-1,12-diazdecane (3) and cyanogendi-N-oxide. Mononuclear NiII and CuII complexes of H2L have a metal:ligand ratio of 1:2 and the ligand coordinates through two hydroxyimino nitrogen atoms, as do most of the (E,E)-dioximes. The hydrogen-bridged NiII complex was converted into its BF
2
+
capped anologue by the reaction with BF3 · Et2O. The reaction of the CuII complex with 2,2′-dipyridyl as an end-cap ligand gave the homotrinuclear complex. Structures for the ligand and its complexes
are proposed in accordance with elemental analysis, magnetic susceptibility measurements, 1H, 13C-n.m.r, IR and MS spectral data. 相似文献
39.
The synthesis of novel metal-free and metallophthalocyanines [Ni(II), Zn(II), Co(II), Cu(II)] were prepared by cyclotetramerization of a novel 4-{2-[2-(1-naphthyloxy)ethoxy]ethoxy}phthalonitrile and the corresponding metal salts (NiCl2, Zn(CH3COO)2, CoCl2 and CuCl2). The structures of the target compounds were confirmed using elemental analysis, IR, 1H NMR, 13C NMR, UV–Vis and MS spectral data. Voltammetric and in situ spectroelectrochemical measurements show that while cobalt phthalocyanine complex gives both metal-based and ring-based redox processes, metal-free, and zinc phthalocyanines show only ring-based reduction and oxidation processes. All complexes decomposed and coated on the electrode as nonconductive film at positive potential window of the electrolyte. An in situ electrocolorimetric method has been applied to investigate color of the electro-generated anionic and cationic forms of the complexes. 相似文献
40.
Zekeriya Altaç Mesut Tekkalmaz 《Journal of Quantitative Spectroscopy & Radiative Transfer》2008,109(4):587-607
Three-dimensional steady-state radiative integral transfer equations (RITEs) for a cubic absorbing and isotropically scattering homogeneous medium are solved using the method of “subtraction of singularity”. Surface integrals and volume integrals are carried out analytically to eliminate singularities, to assure highly accurate solutions, and to reduce the computational time. The resulting system of linear equations for the incident energy is solved iteratively. Six benchmark problems for cold participating media subjected to various combinations of externally uniform/non-uniform diffuse radiation loads are considered. The solutions for the incident energy and the net heat flux components are given in tabular form for scattering albedos of ω=0, 0.5 and 1. 相似文献